First
let's talk about Borosilicate glass: it
is a good high strength glass, it is tough, has good
thermal shock capabilities, and is relatively inexpensive. Borosilicate
glass is a mixture of ~ 13% boric oxide (B2O3) and ~80%silica
(SiO2) (the balance is a mixture of metal oxides). Glasses are
noncrystalline, amorphous materials, distinctly different from
solid state crystals. Typically glass measuring cups, pots, and
pans are made out of borosilicate because of its thermal shock
resistance (Pyrex is a trade name for borosilicate glass). It
is not particularly clear and tends to be less homogenous and
exhibits striae and bubbles more than optical glasses. A 15mm
thick borosilicate glass window absorbs about 20% of the visible
light traveling through it.
Sapphire
(synthetic is our case) is a remarkable material composed of crystallized
Al203 , it is not a glass. Natural sapphire and rubies are essentially
the same thing (corundum) except that trapped impurities give
them coloring. Synthetic sapphire does not have the impurities
which add color but weaken the natural material. Sapphire's incredible
hardness is the reason it is used for bearings in watches and
high precision instrumentation. Sapphire is about 4 times as transparent
to visible light as borosilicate glass, but because it is significantly
stronger a thinner window can be used. Our 3.3 mm window absorbs
about 1/6 of the light that a competitors 15mm borosilicate glass
window would and still provides comparable strength. In addition
sapphire has about 4 times the working temperature (up to 1900C).
Sapphire is significantly harder than glass, it exhibits a Knoop
hardness of 2000 compared to borosilicate glass's Knoop hardness
of 418. On the Mohs scale, borosilicate glass is about 5 (appetite),
where sapphire measures 9 (about the same as silicon carbide just
under diamond). One of the most significant properties of sapphire
in this application is its coefficient of thermal expansion. Sapphire
expands only about 1/6th as much as borosilicate glass does per
degree when it is heated. This is the principle cause of thermal
stress cracking in glass. A thick piece of glass, which is hot
on one side (lamp side) and cold on the other (water side), is
subject to very high mechanical stress because of the difference
in thermal expansion. The thicker a window is, the higher the
stress. Additionally, the thermal conductivity of sapphire is
about 20 times higher than borosilicate glass, it is roughly the
same as the stainless steel and titanium housings. Because of
this higher thermal conductivity and lower absorption of light,
the sapphire window efficiently moves heat from inside the housing
out into the water.
Among
the many qualification tests we put our design through was a wave
slap test determined to measure the strength of the window in
its seat in the face of repeated impacts. We hammer the window
with a 500psi water pulse that is designed to generate and propagate
cracks in the window if there are any design problems. Our sapphire window has been tested over 250,000 cycles when mounted in a THSL without damage. Each pulse was held for about 1 second and then released for about 1 second exerting a 1500 pound force on the window every cycle.
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